{"id":3756,"date":"2019-05-25T01:27:54","date_gmt":"2019-05-25T01:27:54","guid":{"rendered":"https:\/\/www.meetyoucarbide.com\/?p=3756"},"modified":"2020-05-07T07:46:20","modified_gmt":"2020-05-07T07:46:20","slug":"14-common-types-of-porous-materials","status":"publish","type":"post","link":"https:\/\/www.meetyoucarbide.com\/ko\/14%ea%b0%80%ec%a7%80-%ec%9d%bc%eb%b0%98%ec%a0%81%ec%9d%b8-%eb%8b%a4%ea%b3%b5%ec%84%b1-%eb%ac%bc%ec%a7%88\/","title":{"rendered":"\ub2e4\uacf5\uc131 \ubb3c\uc9c8\uc758 14 \uac00\uc9c0 \uc77c\ubc18\uc801\uc778 \uc720\ud615"},"content":{"rendered":"
\n

UPAC\ub294 \uae30\uacf5 \ud06c\uae30 \uaddc\ubaa8\uc5d0 \ub530\ub77c \uae30\uacf5\uc744 \ubbf8\uc138 \uae30\uacf5 (<2nm), \uba54\uc870 \uae30\uacf5 \ub610\ub294 \uba54\uc870 \uae30\uacf5 (2-50nm), \uac70\ub300 \uae30\uacf5 (> 50nm)\uc73c\ub85c \ubd84\ub9ac\ud569\ub2c8\ub2e4. \ucd5c\uc2e0 \uc815\uc758\uc5d0 \ub530\ub974\uba74, \uae30\uacf5\uc740 \ubbf8\uc138 \uae30\uacf5 (<0.7 nm) \ubc0f \ubbf8\uc138 \uadf9 (0.7-2 nm)\uc73c\ub85c \uc138\ubd84\ub418\uba70, 100 nm \ubbf8\ub9cc\uc758 \uc6b0\ubb3c\uc740 \uc9d1\ud569 \uc801\uc73c\ub85c \ub098\ub178 \uae30\uacf5\uc73c\ub85c \uc9c0\uce6d\ub41c\ub2e4. \uc774 \uad6c\uba4d \uc7ac\ub8cc\uc758 \uc774\ub984\uc740 \uc5b4\ub5bb\uac8c \uc0dd\uacbc\uc2b5\ub2c8\uae4c?<\/p>\n\n\n\n

MCM \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

MCM\uc740 Mobil Composition of Matter\uc758 \uc57d\uc790\uc785\ub2c8\ub2e4. \uc8fc\ub85c \uc2e4\ub9ac\ucf58 \uc18c\uc2a4\ub85c \uc5d0\ud2f8 \uc2e4\ub9ac\ucf00\uc774\ud2b8\ub97c \uc0ac\uc6a9\ud558\ub294 Mobil Oil \uc5f0\uad6c\uc6d0\ub4e4\uc740 \ubbf8\uc140 \uae30\ubc18 \uc18c\ud504\ud2b8 \ud15c\ud50c\ub9bf \ubc29\ubc95\uc73c\ub85c \ud569\uc131\ud588\uc2b5\ub2c8\ub2e4. MCM \ucd1d\uc0ac\ub294 MCM-41, MCM-48 \ubc0f MCM-50\uc785\ub2c8\ub2e4. MCM-41\uc740 \uc721\uac01\ud615 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uad6c\uc870\uc774\uba70, 1 \ucc28\uc6d0 \uae30\uacf5 \uad6c\uc870\ub85c \ub9cc\ub4e4\uc5b4\uc9c4 \uaddc\uce59\uc801\uc778 \uc6d0\ud1b5\ud615 \uba54\uc870 \ud3ec\uc5b4\uc758 \ubc30\uc5f4\uc785\ub2c8\ub2e4. \uba54\uc18c \ud3ec\uc5b4 \uc9c1\uacbd\uc740 2-6.5 nm\uc5d0\uc11c \uc870\uc808 \uac00\ub2a5\ud558\uba70 \ud070 \ube44 \ud45c\uba74\uc801. \ubd84 \uc790\uccb4\uc640 \ube44\uad50\ud558\uc5ec, MCM-41\uc5d0\ub294 \ube0c nst \uc2a4 \ud14c\ub4dc \uc0b0 \ubd80\uc704\uac00 \uc5c6\ub2e4. Si-O \uacb0\ud569\uc740 \ubcbd\uc774 \uc587\uace0 \uc2e4\ub9ac\ucf58 \ub2e8\uc704\uc758 \ub0ae\uc740 \uad50\ud658 \uc728\ub85c \uc778\ud574 \ub053\ub294 \ubb3c\uc5d0\uc11c \uac00\uc218 \ubd84\ud574 \ubc0f \uc7ac\uac00 \uad50\ub418\uc5b4 \uad6c\uc870\uc801 \uc190\uc0c1\uc744 \ucd08\ub798\ud569\ub2c8\ub2e4. \ub530\ub77c\uc11c \uc5f4 \uc548\uc815\uc131\uc774 \uc88b\uc9c0 \uc54a\uc2b5\ub2c8\ub2e4. MCM-41\uc758 \ud569\uc131\uc5d0 \uad00\ud55c \ucd5c\ucd08\uc758 \ub17c\ubb38\uc740 1992 \ub144 JAC\uc5d0 \ubc1c\ud45c\ub418\uc5c8\uc73c\uba70 \uc778\uc6a9\uc740 \uac70\uc758 12,000 \uac1c\uc758 \uc778\uc6a9\uc744 \uac00\uc9c0\uace0 \uc788\uc2b5\ub2c8\ub2e4. (J. Am. Chem. Soc., 1992, 114 (27), pp 10834-10843) MCM-48\uc740 3 \ucc28\uc6d0 \uc801\uc73c\ub85c \uc0c1\ud638 \uc5f0\uacb0\ub41c \uc140 \uad6c\uc870\ub97c \uac16\ub294\ub2e4. MCM-50\uc740 \ub77c\uba5c\ub77c \uad6c\uc870\uc774\uba70, \uacc4\uba74 \ud65c\uc131\uc81c-\ud615\uc131 \uce35\uc758 \uc81c\uac70\uc2dc \ub77c\uba5c\ub77c \uad6c\uc870\uac00 \ubd95\uad34\ub418\uae30 \ub54c\ubb38\uc5d0 "\uacf5\ud3ec \uc131"\ubcf4\ub2e4\ub294 "\uba54\uc870 \uad6c\uc870"\ub85c\ub9cc \uc9c0\uce6d \ub420 \uc218 \uc788\uace0, \uae30\uacf5\uc774 \uc5c6\uae30 \ub54c\ubb38\uc5d0, \uc774\ub294 \uae4a\uc740 \uac83\uc740 \uc544\ub2c8\ub2e4. <\/strong><\/p>\n\n\n\n

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\uadf8\ub9bc 1 MCM-41 \ud569\uc131 \uba54\ucee4\ub2c8\uc998 \ub2e4\uc774\uc5b4\uadf8\ub7a8, \uc0ac\uc6a9 \ub41c \uacc4\uba74 \ud65c\uc131\uc81c\ub294 \uc74c\uc774\uc628 \uc131 \uacc4\uba74 \ud65c\uc131\uc81c<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

SBA \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

SBA\ub294 Santa Barbara Amorphous\uc758 \uc57d\uc790\uc785\ub2c8\ub2e4. \uadf8\uc911\uc5d0\uc11c\ub3c4 \ud070 \uc774\ub984\uc740 SBA-15\uc785\ub2c8\ub2e4. SBA-15\ub294 1998 \ub144 Fudan University\uc758 \uad50\uc0ac \uc778 Zhao Dongyuan\uc5d0 \uc758\ud574 \ubbf8\uad6d \uce98\ub9ac\ud3ec\ub2c8\uc544 \ub300\ud559\uad50 \uc0b0\ud0c0 \ubc14\ubc14\ub77c\uc5d0\uc11c \ub300\ud559\uc6d0 \uacfc\uc815\uc744 \ub9c8\uce5c \ud6c4 \ucc98\uc74c\uc73c\ub85c \ud569\uc131\ub418\uc5c8\uc2b5\ub2c8\ub2e4. \uadf8 \ud574\uc5d0 Science\uc5d0 \ucd9c\ud310\ub418\uc5c8\uc73c\uba70 10,000 \ud68c \uc774\uc0c1 \uc778\uc6a9\ub418\uc5c8\uc2b5\ub2c8\ub2e4 ( \uacfc\ud559 1998 \ub144 1 \uc6d4 23 \uc77c : 279, 5350, 548-552.). SBA \uacc4\uc5f4 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc2e4\ub9ac\uce74 \ubb3c\uc9c8\uc740 \ube14\ub85d \ud615 \uacc4\uba74 \ud65c\uc131\uc81c\ub97c \uc0ac\uc6a9\ud558\ub294 \uc5f0\uc9c8 \uc8fc \ud615\ubc95\uc744 \uc0ac\uc6a9\ud558\uc5ec \ud569\uc131\ub41c\ub2e4; \uadf8\uac83\uc758 \uae30\uacf5 \ud06c\uae30\ub294 5-30 nm\uc758 \ubc94\uc704\uc5d0\uc11c \uc870\uc815 \uac00\ub2a5\ud558\ub2e4. SBA-15\ub294 \uc140 \ubcbd \ub450\uaed8\uac00 3-6 nm \uc778 \uc784\uc758\uc758 \uc21c\uc11c\ub85c \uc815\ub82c \ub41c \uba87 \uac1c\uc758 \uba54\uc870 \uae30\uacf5 \ub610\ub294 \uae30\uacf5\uc744 \uac16\ub294 \uc77c\ub828\uc758 \uc721\uac01\ud615 \ud3c9\ud589 \uc6d0\ud1b5\ud615 \ucc44\ub110\ub85c \uad6c\uc131\ub429\ub2c8\ub2e4. SBA-15\uc758 \ub450\uaebc\uc6b4 \uc138\ud3ec\ubcbd\uc73c\ub85c \uc778\ud574 \uc7ac\ub8cc\uc758 \uc5f4\uc218 \uc548\uc815\uc131\uc774 MCM \uc2dc\ub9ac\uc988\uc758 \uc5f4\uc218 \uc548\uc815\uc131\ubcf4\ub2e4 \uc6b0\uc218\ud569\ub2c8\ub2e4. SBA-15\ub294 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ubb3c\uc9c8\uc744 \ubaa8\ub450 \ud3ec\ud568\ud558\ub294 \ub2e4\ucc28\uc6d0 \ub2e4\uacf5\uc131 \ubb3c\uc9c8\uc785\ub2c8\ub2e4. \uc18c\uc131 \uacf5\uc815 \ub3d9\uc548 \uae30\uacf5 \ubcbd\uc5d0 \ub0b4\uc7a5 \ub41c \uacc4\uba74 \ud65c\uc131\uc81c\ub97c \uc81c\uac70\ud558\uc5ec \ubbf8\uc138 \ub2e4\uacf5\uc131 \uad6c\uc870\ub97c \uc0dd\uc131 \ud560 \uc218 \uc788\uc2b5\ub2c8\ub2e4.<\/p>\n\n\n\n

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\uae30\uacf5 \ud06c\uae30\uac00 \ub2e4\ub978 SBA-15\uc758 \uadf8\ub9bc 2 (\uc67c\ucabd) TEM \uc774\ubbf8\uc9c0. (\uc624\ub978\ucabd) 3 \ube14\ub85d \uacc4\uba74 \ud65c\uc131\uc81c\uc758 \uc18c\uc218\uc131 \ub9d0\ub2e8\uc740 \ud615\uc131\ub41c \uc2e4\ub9ac\uce74\uc758 \uae30\uacf5 \ubcbd\uc73c\ub85c \ub4e4\uc5b4\uac08 \uac83\uc774\ub2e4. \uc18c\uc131 \ud6c4 \ubbf8\uc138 \uad6c\uba4d<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

HMM \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

HMM\uc740 Hiroshima Mesoporous Material\uc758 \uc57d\uc790\uc774\uba70 2009 \ub144 Hiroshima University\uc758 \uc5f0\uad6c\uc6d0\ub4e4\uc5d0 \uc758\ud574 \ucc98\uc74c\uc73c\ub85c \uc900\ube44\ub418\uc5c8\uc2b5\ub2c8\ub2e4. HMM\uc740 \uae30\uacf5 \ud06c\uae30\uac00 4-15nm\uc774\uace0 \uc870\uc815 \uac00\ub2a5\ud55c \uc678\uacbd\uc774 20-80nm \uc778 \uad6c\ud615 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc2e4\ub9ac\ucf58 \ubb3c\uc9c8\uc785\ub2c8\ub2e4. \ud569\uc131 \ub2e8\uacc4\uc5d0\uc11c, \uc800\uc790\ub294 \uba3c\uc800 \uc624\uc77c \/ \ubb3c \/ \uacc4\uba74 \ud65c\uc131\uc81c \ud63c\ud569 \uc6a9\uc561\uc744 \ud1b5\ud574 \uc5d0\uba40\uc83c \uc561 \uc801\uc744 \ud615\uc131 \ud55c \ub2e4\uc74c, \ud15c\ud50c\ub9bf\uc73c\ub85c\uc11c \uc778\uc2dc \ud29c (in situ) \uc0dd\uc131 \ub41c \ud3f4\ub9ac\uc2a4\ud2f0\ub80c \uc785\uc790\ub85c \uc2e4\ub9ac\ucf58\uc744 \uc131\uc7a5\uc2dc\ucf1c, \ud15c\ud50c\ub9bf\uc774 \uc81c\uac70 \ub41c \ud6c4 \uad6c\ud615 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc2e4\ub9ac\uce74\ub97c \uc0dd\uc131\ud55c\ub2e4. (\ubbf8 \uacf5\uc131 \ubc0f \uba54\uc870 \uae30\uacf5 \uc7ac\ub8cc 120 (2009) 447-453.)<\/p>\n\n\n\n

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\uadf8\ub9bc 3 HMM \ud569\uc131 \uba54\ucee4\ub2c8\uc998 \ub2e4\uc774\uc5b4\uadf8\ub7a8 \ubc0f \uc81c\ud488 SEM \ubc0f TEM \uc774\ubbf8\uc9c0<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

TUD \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

TUD\ub294 Delft University of Technology\ub85c\ub3c4 \uc54c\ub824\uc9c4 Technische Universiteit Delft\uc758 \uc57d\uc790\uc785\ub2c8\ub2e4. \uc804\uc790 \ud604\ubbf8\uacbd \uc0ac\uc9c4\uc5d0\uc11c TUD-1\uc740 400-1000 m2 \/ g\uc758 \ud45c\uba74\uc801\uacfc 2.5 ~ 25 nm\uc758 \uac00\ubcc0 \uba54\uc870 \ud3ec\uc5b4\ub97c \uac16\ub294 \ud3fc\uc73c\ub85c \ub098\ud0c0\ub0a9\ub2c8\ub2e4. \uc7ac\ub8cc\uc758 \ud569\uc131\uc5d0\ub294 \uacc4\uba74 \ud65c\uc131\uc81c\uac00 \uc5c6\uc73c\uba70 \uc720\uae30 \uc8fc\ud615 \uc81c\ub85c \ud2b8\ub9ac \uc5d0\ud2f8 \uc544\ubbfc\uc774 \uc0ac\uc6a9\ub429\ub2c8\ub2e4. \uae30\uacf5 \uad6c\uc870\ub294 \uc720\uae30 \uc8fc \ud615\uc81c \ubc0f \uc2e4\ub9ac\ucf58 \uc18c\uc2a4\uc758 \ube44\uc728\uc744 \uc870\uc815\ud568\uc73c\ub85c\uc368 \uc81c\uc5b4 \ub420 \uc218\uc788\ub2e4. (Chem. Commun., 2001, 713-714)<\/p>\n\n\n\n

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\uadf8\ub9bc 4 (\uc67c\ucabd) TDU-1\uc758 SEM \uc774\ubbf8\uc9c0, (\uc624\ub978\ucabd) TDU-1\uc744 \ub2e8\ub2e8\ud55c \ud15c\ud50c\ub9bf\uc73c\ub85c \ud569\uc131 \ud55c \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ud0c4\uc18c \uc7ac\ub8cc<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

FSM \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

FSM\uc740 \uc811\ud78c \uc2dc\ud2b8 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc7ac\ub8cc\uc758 \uc904\uc784\ub9d0\uc785\ub2c8\ub2e4. \uadf8 \uc774\ub984\uc758 \ub9ac\ud130\ub7f4 \ubc88\uc5ed\uc740 \uc811\ud78c \uc2dc\ud2b8 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ubb3c\uc9c8\uc785\ub2c8\ub2e4. FSM \ud569\uc131\uc740 \uc54c\uce7c\ub9ac \uc870\uac74 \ud558\uc5d0\uc11c \uce35\uc0c1 \uc2e4\ub9ac\ucf00\uc774\ud2b8 \ubb3c\uc9c8 \uce74\ub124 \ub9c8\uc774\ud2b8 \ubc0f \uc7a5\uc1c4 \uc54c\ud0ac \ud2b8\ub9ac\uba54\ud2f8 \uc544\ubbfc (ATMA)\uc758 \ud569\uc131\uc774\uba70, 3 \ucc28\uc6d0 \uc721\uac01\ud615 \uba54\uc18c \ud3ec\ub7ec\uc2a4 \uc2e4\ub9ac\uce74 \ubb3c\uc9c8\uc758 \uc881\uc740 \uae30\uacf5 \ud06c\uae30 \ubd84\ud3ec\ub97c \uc5bb\uae30 \uc704\ud574 \ud63c\ud569 \ucc98\ub9ac \uc774\uc628 \uad50\ud658\uc774 \uc77c\uc5b4\ub09c\ub2e4. FSC\uc758 \ube44 \ud45c\uba74\uc801\uc740 650-1000 m2 \/ g\uc774\uba70 \uae30\uacf5 \ud06c\uae30\ub294 1.5-3 nm\uc785\ub2c8\ub2e4. (Bull. Chem. Soc. Jpn., 69, No. 5 (1996))<\/p>\n\n\n\n

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\uadf8\ub9bc 5 FSM\uc758 TEM \ub2e4\uc774\uc5b4\uadf8\ub7a8<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

\ud0a4\ud2b8 \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

KIT\ub294 \ud55c\uad6d \uacfc\ud559 \uae30\uc220\uc6d0\uc758 \uc57d\uc790 \uc778 \uacf5\uc2dd\uc801\uc778 \uc9c4\uc220\uc744 \ucc3e\uc9c0 \ubabb\ud588\ub2e4. \ub610\ud55c SBA-15 (\uc785\ubc29\uccb4 p6mm) \ub2e8\ubc29\ud5a5 \uae30\uacf5 \uad6c\uc870\uc640\ub294 \ub2e4\ub978 \uc815\ub82c \ub41c \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc2e4\ub9ac\uce74 \uc7ac\ub8cc\uc5d0 \uc18d\ud558\uba70, KIT-6 (\uc785\ubc29\uccb4 la3d)\uc740 \uc785\ubc29\uccb4 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uad6c\uc870\ub97c \uc0c1\ud638 \uc5f0\uacb0\ud588\uc2b5\ub2c8\ub2e4. KIT-6\uc758 \ud569\uc131\uc5d0\uc788\uc5b4\uc11c, \uad6c\uc870 \uc9c0\uc2dc \uc81c\ub85c\uc11c \ud2b8\ub9ac \ube14\ub85d \uacc4\uba74 \ud65c\uc131\uc81c (EO20PO70EO20)\uc640 \ubd80\ud0c4\uc62c\uc758 \ud63c\ud569\ubb3c\uc744 \uc0ac\uc6a9 \ud558\uc600\ub2e4. KIT-6 \uae30\uacf5 \ud06c\uae30\ub294 4-12 nm\uc5d0\uc11c \uc870\uc815\ud560 \uc218 \uc788\uc73c\uba70 \ube44 \ud45c\uba74\uc801\uc740 960-2200 m2 g-1\uc785\ub2c8\ub2e4. (Chem. Commun., 2003, 2136-2137)<\/p>\n\n\n\n

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\uadf8\ub9bc 6 (\uc67c\ucabd) SBA-15 p6mm \ubc0f KIT-6 la3d\uc758 \uad6c\uc870 \ub2e4\uc774\uc5b4\uadf8\ub7a8, (\uc624\ub978\ucabd) KIT-6\uc758 TEM \uc774\ubbf8\uc9c0<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

CMK \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

\uba54\uc870 \ud3ec\ub7ec\uc2a4 \uce74\ubcf8\uc744 \ud569\uc131\ud558\ub294 \uc77c\ubc18\uc801\uc778 \ubc29\ubc95\uc740 \ud558\ub4dc \ud15c\ud50c\ub9bf \ubc29\ubc95\uc785\ub2c8\ub2e4. MCM-48 \ubc0f SBA-15\uc640 \uac19\uc740 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ubd84 \uc790\uccb4\ub294 \uc801\uc808\ud55c \uc804\uad6c\uccb4\ub97c \uc120\ud0dd\ud558\uace0, \uc0b0\uc758 \ucd09\ub9e4 \ud558\uc5d0\uc11c \uc804\uad6c\uccb4\ub97c \ud0c4\ud654\uc2dc\ud0a4\uace0 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ubb3c\uc9c8\uc758 \uae30\uacf5\uc5d0 \uce68\ucc29\uc2dc\ud0a8 \ub2e4\uc74c NaOH \ub610\ub294 HF \uba54\uc870 \ud3ec\ub7ec\uc2a4 SiO2\ub85c \uc6a9\ud574\uc2dc\ud0a4\ub294 \uc8fc\ud615\uc73c\ub85c \uc0ac\uc6a9\ub429\ub2c8\ub2e4. \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uce74\ubcf8\uc744 \uc5bb\uc744 \uc218 \uc788\uc2b5\ub2c8\ub2e4. 1999 \ub144, Ryoo\ub294 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc7ac\ub8cc\ub97c \ub2e8\ub2e8\ud55c \ud15c\ud50c\ub9bf\uc73c\ub85c \uc0ac\uc6a9\ud558\uc5ec \ub2e4\ub978 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc7ac\ub8cc\ub97c \ubcf5\uc81c\ud558\ub294 \ub370 \uc131\uacf5\ud588\uc2b5\ub2c8\ub2e4. CMK\ub77c\ub294\uc774 \uc77c\ub828\uc758 \uc7ac\ub8cc. \ub610\ud55c \uacf5\uc2dd\uc801\uc778 \uc774\ub984\uc740 \ucc3e\uc9c0 \ubabb\ud588\uc9c0\ub9cc, \uc544\ub9c8\ub3c4 \ud0c4\uc18c \ubd84 \uc790\uccb4\uc640 \ud55c\uad6d\uc758 \uacb0\ud569 \ub41c \uc774\ub984\uc740 \ucc3e\uc744 \uc218 \uc788\uc2b5\ub2c8\ub2e4. \uadf8\ub294 MCM-48, SBA-1, SBA-15 \ubc0f KIT-6\uc744 \uc8fc\ud615\uc73c\ub85c \uc0ac\uc6a9\ud558\uc5ec CMK-1, CMK-2, CMK-3, CMK-8 \ubc0f CMK-9 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ud0c4\uc18c \ubd84 \uc790\uccb4 \uc7ac\ub8cc\ub97c \uc5f0\uc18d\uc801\uc73c\ub85c \uc0dd\uc0b0\ud588\uc2b5\ub2c8\ub2e4. CMK-3\uc740 \uc881\uc740 \uae30\uacf5 \ud06c\uae30 \ubd84\ud3ec, \ub192\uc740 \ube44 \ud45c\uba74\uc801 (1000-2000 m2 \/ g), \ud070 \uae30\uacf5 \ubd80\ud53c 1.35\ub97c \uac16\ub294 2 \ucc28\uc6d0 6 \uac01\ud615 \uad6c\uc870\uc774\ub2e4 (J. Phys. Chem. B, 103, 37, 1999.). cm3 \/ g) \ubc0f \uac15\uc0b0 \ubc0f \uc54c\uce7c\ub9ac \uc800\ud56d\uc131\uc740 \uc6b0\uc218\ud55c \ucd09\ub9e4 \ub2f4\uccb4\uc774\ub2e4.<\/p>\n\n\n\n

\"\"
\uadf8\ub9bc 7 CMK-1 \ubc0f CMK-3\uc758 TEM \uc774\ubbf8\uc9c0<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

FDU \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

FDU \uc2dc\ub9ac\uc988\ub294 Fudan University\uc758 \uc57d\uc790\uc774\uba70 Fudan University\ub85c \ub3cc\uc544\uc628 \ud6c4 Zhao Dongyuan \uad50\uc0ac\uac00 \uc218\ud589 \ud55c \uc791\uc5c5\uc785\ub2c8\ub2e4. FDU\ub294 \uc5f0\uc9c8 \ud15c\ud50c\ub808\uc774\ud2b8 \ubc29\ubc95\uc73c\ub85c \ud569\uc131 \ub41c \uc77c\ub828\uc758 \ud398\ub180 \uc218\uc9c0\uc785\ub2c8\ub2e4. \uc815\ub82c \ub41c \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ud0c4\uc18c \uc7ac\ub8cc\ub294 \uace0\uc628 \ud0c4\ud654\uc5d0 \uc758\ud574 \ud569\uc131 \ub420 \uc218 \uc788\uace0 \uad6c\ud615 \uae30\uacf5\uc73c\ub85c \uad6c\uc131\ub41c\ub2e4. \uad6c\uc870 \uc9c0\uc2dc \uc81c\ub85c\uc11c \uacc4\uba74 \ud65c\uc131\uc81c\uc758 \uc0ac\uc6a9, \uc6d0\ub8cc\ub85c\uc11c \ud398\ub180 \uc218\uc9c0 \uc804\uad6c\uccb4\uc758 \uc0ac\uc6a9, \uc6a9\ub9e4 \uc99d\ubc1c \uc790\uae30 \uc870\ub9bd\ubc95\uc5d0 \uc758\ud574 \uc9c8\uc11c \uc815\uc5f0\ud55c \uad6c\uc870\ub97c \uc5bb\ub294 \uac83\ub3c4 \ub3d9\uc77c\ud558\ub2e4. (Angew. Chem. Int. Ed. 2005, 44, 7053-7045)<\/p>\n\n\n\n

\"\"
\uadf8\ub9bc 8 \uace0\uc628 \ud0c4\ud654 \ud6c4 FDU-15 \ubc0f FDU-16<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

\uc2a4\ud0c0 \ubcf8 \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

\uc2a4\ud0c0 \ubcf8\uc740 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ud0c4\uc18c \uc7ac\ub8cc\uc758 \uc774\ub984\uc785\ub2c8\ub2e4. \uc6d0\ub798 Starbon\uc740 Starch\uc758 sol-gel \ubc29\ubc95\uc73c\ub85c York University\uc758 \uc5f0\uad6c\uc6d0\ub4e4\uc5d0 \uc758\ud574 \ud569\uc131 \ub41c \ud6c4 \ud0c4\ud654\ub418\uae30 \ub54c\ubb38\uc785\ub2c8\ub2e4. \ub530\ub77c\uc11c \uc774\ub984\uc740 Starbon\uc774\uba70 \ube0c\ub79c\ub4dc \uc774\ub984\uc740 "Starbon"\uc785\ub2c8\ub2e4. \ube44 \ud45c\uba74\uc801 500 m2 \/ g \uc778 2.0 cm3 \/ g\uc758 \uc2a4\ud0c0 \ubcf8 \uba54\uc18c \ud3ec\uc5b4 \ubd80\ud53c\ub294 \ucd09\ub9e4 \ub2f4\uccb4, \uac00\uc2a4 \ud761\ucc29\uc81c \ub610\ub294 \uc815\uc218 \uc81c\ub85c \uc0ac\uc6a9\ub420 \uc218\uc788\ub2e4. \uc774\uc81c \uc2a4\ud0c0 \ubcf8 \uc6d0\ub8cc\ub294 \ud399\ud2f4\uacfc \uc54c\uae34\uc0b0\uc73c\ub85c \ud655\uc7a5 \ub420 \uc218 \uc788\uc2b5\ub2c8\ub2e4.<\/p>\n\n\n\n

\"\"
\uadf8\ub9bc 9 (\uc67c\ucabd) \uc2a4\ud0c0 \ubcf8 \ud569\uc131 \ub2e8\uacc4, (\uc624\ub978\ucabd) \uc2a4\ud0c0 \ubcf8\uc758 SEM \uc774\ubbf8\uc9c0<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

ZSM \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

ZSM\uc740 Zeolite Socony Mobil\uc758 \uc57d\uc790\uc774\uba70 ZSM-5\ub294 Socony Mobil Corporation\uc774 \ubc1c\uacac \ud55c \ub2e4\uc12f \ubc88\uc9f8 Zeolite \uc778 \uc0c1\ud45c\uba85\uc785\ub2c8\ub2e4. 1975 \ub144\uc5d0 \ud569\uc131 \ub41c Nature\ub294 1978 \ub144\uc5d0 \uadf8 \uad6c\uc870\ub97c\ubcf4\uace0\ud588\ub2e4. ZSM-5\ub294 \uc815\uc0ac\uac01\ud615 \uc2dc\uc2a4\ud15c\uc774\ub2e4. \ub192\uc740 \uaddc\uc18c \ubc0f 5 \uc6d0 \uace0\ub9ac\ub97c \uac16\ub294 3 \ucc28\uc6d0 \uad50\ucc28 \ucc44\ub110\uc744 \uac16\ub294 \uc77c\uc885\uc758 \uc81c\uc62c\ub77c\uc774\ud2b8 \ubd84 \uc790\uccb4\uc774\ub2e4. \uce5c \uc720\uc131\uc774\uace0 \uc18c\uc218\uc131\uc774\uba70, \uc5f4 \ubc0f \uc5f4\uc218 \uc548\uc815\uc131\uc774 \ub192\uc73c\uba70, \ub300\ubd80\ubd84\uc758 \uae30\uacf5\uc740 \uc9c1\uacbd\uc774 \uc57d 0.55 nm \uc778 \ud640 \uc81c\uc62c\ub77c\uc774\ud2b8\uc774\ub2e4.<\/p>\n\n\n\n

\"\"
\uadf8\ub9bc 10 TPABr \ud569\uc131 ZSM-5<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n

AlPO \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

AlPO\ub294 \uc0b0\uc774\uc5c6\ub294 \ubbf8\uc138 \ub2e4\uacf5\uc131 \uc54c\ub8e8\ubbf8 \ub178 \ud3ec\uc2a4\ud398\uc774\ud2b8 \ubd84 \uc790\uccb4\uc758 \uc57d\uc790\ub85c 1980 \ub144\ub300 \uc774\ud6c4 \ubbf8\uad6d UOP Company\uc5d0\uc11c \uac1c\ubc1c \ud55c "2 \uc138\ub300 \ubd84 \uc790\uccb4"\uc785\ub2c8\ub2e4. \uc774\ub4e4 \ubd84 \uc790\uccb4 \ud504\ub808\uc784 \uc6cc\ud06c\ub294 \ub3d9\uc77c\ud55c \uc591\uc758 AlO4- \ubc0f PO4- \uc0ac\uba74\uccb4\ub85c \uad6c\uc131\ub418\uba70 \uc804\uae30\uc801\uc73c\ub85c \uc911\uc131\uc774\uba70 \uc57d\ud55c \uc0b0-\ucd09\ub9e4 \ud2b9\uc131\uc744 \ub098\ud0c0\ub0b8\ub2e4. \ud5e4\ud14c\ub85c \uc6d0\uc790\ub97c \ub3c4\uc785\ud568\uc73c\ub85c\uc368, AlPO \uc81c\uc62c\ub77c\uc774\ud2b8 \uace8\uaca9\uc758 \uc6d0\ub798 \uc804\ud558 \uade0\ud615\uc774 \ubd84\ud574 \ub420 \uc218\uc788\uc5b4\uc11c, \uc774\uc758 \uc0b0\ub3c4, \ud761\ucc29 \uc131\ub2a5 \ubc0f \ucd09\ub9e4 \ud65c\uc131\uc774 \uc0c1\ub2f9\ud788 \uac1c\uc120\ub418\uc5c8\ub2e4. AlPO4-5\uc758 \uace8\uaca9 \uad6c\uc870\ub294 6 \uac01\ud615 \uc2dc\uc2a4\ud15c\uc5d0 \uc18d\ud558\uba70 0.76 nm\uc758 \uae30\uacf5 \ud06c\uae30\ub97c \uac16\ub294 \uc804\ud615\uc801\uc778 12 \uc6d0 \uace0\ub9ac \uc8fc \ucc44\ub110\ub85c \ubc29\ud5a5\uc871\uc758 \uad6c\uc870\uc640 \ube44\uc2b7\ud558\ub2e4.<\/p>\n\n\n\n

SAPO \uc2dc\ub9ac\uc988<\/strong><\/h2>\n\n\n\n

SAPO\ub294 Silicoaluminophosphate\uc758 \uc57d\uc790\uc774\uba70, SAPO-34\ub294 1982 \ub144 UCC\uc5d0\uc11c \ucc98\uc74c\ubcf4\uace0 \ud55c \ubd84 \uc790\uccb4\uc774\uba70 34\ub294 \ucf54\ub4dc\uc785\ub2c8\ub2e4. SAPO-34\uc758 \uace8\uaca9\uc740 PO2 +, SiO2, AlO2-\ub85c \uad6c\uc131\ub418\uba70 3 \ucc28\uc6d0 \uad50\ucc28 \ucc44\ub110, 8 \ub9c1 \uae30\uacf5 \uc9c1\uacbd \ubc0f \uc911\uac04 \uc0b0 \uc704\uce58\ub97c\uac00\uc9d1\ub2c8\ub2e4. \ud761\ucc29 \ubd84\ub9ac \ubc0f \ub9c9 \ubd84\ub9ac\ubfd0\ub9cc \uc544\ub2c8\ub77c \uc6b0\uc218\ud55c \uc131\ub2a5\uc744 \ubcf4\uc5ec \uc8fc\uc5c8\ub2e4. SAPO-11\uc758 \uc870\uc131\uc740 Si, P, Al \ubc0f O 4 \uc885\uc774\uba70, \uadf8 \uc870\uc131\uc740 \uad11\ubc94\uc704\ud558\uac8c \ubcc0\uacbd \ub420 \uc218 \uc788\uc73c\uba70, \uc0dd\uc131\ubb3c\uc758 \uaddc\uc18c \ud568\ub7c9\uc740 \ud569\uc131 \uc870\uac74\uc5d0 \ub530\ub77c \ub2ec\ub77c\uc9c4\ub2e4. \ud0c0\uc6d0\ud615 \uad6c\uba4d\uc5d0 1 \ucc28\uc6d0 10- \ub9c1 \uad6c\uc870\ub97c \uac16\ub294 SAPO-11 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc81c\uc62c\ub77c\uc774\ud2b8. SAPO \ubd84 \uc790\uccb4 \ud504\ub808\uc784 \uc6cc\ud06c\ub294 \uc74c\uc804\ud558\ub97c \ub760\uae30 \ub54c\ubb38\uc5d0 \uc591\uc774\uc628 \uad50\ud658\uc774 \uac00\ub2a5\ud558\uba70 \uc591\uc131\uc790 \uc0b0\ub3c4\ub97c \uac00\uc9c4\ub2e4. SAPO \ubd84 \uc790\uccb4\ub294 \ud761\ucc29\uc81c, \ucd09\ub9e4 \ubc0f \ucd09\ub9e4 \ub2f4\uccb4\ub85c\uc11c \uc0ac\uc6a9\ub420 \uc218\uc788\ub2e4.<\/p>\n\n\n\n

\"\"
\uadf8\ub9bc 11 \uacb0\uc815\ud654 \uc2dc\uac04\uc774 48 \uc2dc\uac04 \uc778 SAPO-11\uc758 SEM \uc774\ubbf8\uc9c0<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n


\uc77c\ubc18\uc801\uc73c\ub85c \uc0ac\uc6a9\ub418\uc9c0 \uc54a\ub294 \uba87 \uac00\uc9c0 \ub2e4\ub978 \ub2e4\uacf5\uc131 \uc7ac\ub8cc\uac00 \uc788\uc2b5\ub2c8\ub2e4.
MSU <\/strong> (Michigan State University)\ub294 Pinnavaia \ub4f1\uc774 \uac1c\ubc1c \ud55c \uc77c\ub828\uc758 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ubd84 \uc790\uccb4\uc785\ub2c8\ub2e4. \ubbf8\uc2dc\uac04 \ub300\ud559\uad50 MSU-X (MSU-1, MSU-2 \ubc0f MSU-3). MSU-V, MSU-G\ub294 \ub2e4\uce35 \uc18c\ud3ec\uc758 \uce35 \uad6c\uc870\ub97c \uac00\uc9c0\uace0 \uc788\uc2b5\ub2c8\ub2e4.<\/p>\n\n\n\n

HMS <\/strong><\/h2>\n\n\n\n

(\uc721\uac01 \uba54\uc870 \ud3ec\ub7ec\uc2a4 \uc2e4\ub9ac\uce74)\ub294 Pinnavaia et al.\uc5d0 \uc758\ud574 \uac1c\ubc1c \ub41c \uba54\uc870 \ud3ec\ub7ec\uc2a4 \ubd84 \uc790\uccb4\uc774\uba70, \uc774\ub294 \ub610\ud55c \ub0ae\uc740 \ucc28\uc218\ub97c \uac16\ub294 \uc721\uac01\ud615 \uad6c\uc870\uc774\ub2e4.<\/p>\n\n\n\n

APM<\/strong> <\/h2>\n\n\n\n

Stucky \ub4f1\uc758 \ucd08\uae30 \uc5f0\uad6c \uc778 \uc0b0\uc131 \uc900\ube44\ub41c \uba54\uc870 \uad6c\uc870\ub294 \uc0b0\uc131 \uc870\uac74 \ud558\uc5d0\uc11c \uc81c\uc870\ub418\uc5c8\uc73c\uba70 MCM \uacc4\uc5f4\uc758 \ud569\uc131 \uacf5\uc815 (\uc54c\uce7c\ub9ac\uc131 \ub9e4\uccb4)\uc758 \ud655\uc7a5\uc774\uc5c8\ub2e4.
\uc774\ub984\uc774 \ub9e4\uc6b0 \ub3c5\ucc3d\uc801 \uc77c\ubfd0\ub9cc \uc544\ub2c8\ub77c \ub2e4\uacf5\uc131 \uc7ac\ub8cc\uc758 \uc801\uc6a9 \ub610\ud55c \ub9e4\uc6b0 \uad11\ubc94\uc704\ud569\ub2c8\ub2e4.<\/p>\n\n\n\n

1. \ud6a8\uc728\uc801\uc778 \uac00\uc2a4 \ubd84\ub9ac\ub9c9;<\/p>\n\n\n\n

2. \ud654\ud559 \uacf5\uc815 \ucd09\ub9e4 \ub9c9;<\/p>\n\n\n\n

\uace0\uc18d \uc804\uc790 \uc2dc\uc2a4\ud15c\uc744\uc704\ud55c 3.Substrate \ubb3c\uc790;<\/p>\n\n\n\n

4. \uad11\ud1b5\uc2e0 \uc7ac\ub8cc\uc758 \uc804\uad6c\uccb4;<\/p>\n\n\n\n

5. \uace0\ud6a8\uc728 \ub2e8\uc5f4\uc7ac;<\/p>\n\n\n\n

\uc5f0\ub8cc \uc804\uc9c0\uc6a9 \ub2e4\uacf5\uc131 \uc804\uadf9; 6.<\/p>\n\n\n\n

7. \ubc30\ud130\ub9ac \uc6a9 \ubd84\ub9ac \ub9e4\uccb4 \ubc0f \uc804\uadf9;<\/p>\n\n\n\n

8. \uc800\uc7a5 \ub9e4\uccb4\uc758 \uc5f0\ub8cc (\ucc9c\uc5f0 \uac00\uc2a4 \ubc0f \uc218\uc18c \ud3ec\ud568); <\/p>\n\n\n\n

9. \ud658\uacbd \uc815\ud654 \ud761\uc218\uc81c\uc758 \uc120\ud0dd;<\/p>\n\n\n\n

10. \ud2b9\uc218 \uc7ac\uc0ac\uc6a9 \uac00\ub2a5\ud55c \ud544\ud130. \uc774\ub7ec\ud55c \uc751\uc6a9 \ud504\ub85c\uadf8\ub7a8\uc740 \uc0b0\uc5c5 \uc751\uc6a9 \ud504\ub85c\uadf8\ub7a8\uacfc \uc0ac\ub78c\ub4e4\uc758 \uc77c\uc0c1 \uc0dd\ud65c\uc5d0 \ud070 \uc601\ud5a5\uc744 \ubbf8\uce69\ub2c8\ub2e4.<\/p>\n\n\n\n


\ucc38\uace0 \ubb38\ud5cc :<\/strong>1. J. Am. \ud654\ud559 Soc., 1992, 114 (27), pp 10834-10843.2. \uacfc\ud559 1998 \ub144 1 \uc6d4 23 \uc77c : 279, 5350, 548-552.3. \ubbf8\uc138 \ub2e4\uacf5\uc131 \ubc0f \uba54\uc870 \ub2e4\uacf5\uc131 \ubb3c\uc9c8 120 (2009) 447-453.4. \ud654\ud559 Commun., 2001, 713-714.5. \ud669\uc18c. \ud654\ud559 Soc. Jpn., 69, No. 5 (1996) 6. J. Chem. Soc., Chem. \ucf54\ubb8c. 1993, 8, 680.7. \ud654\ud559 Commun., 2003, 2136-2137.8. J. Phys. \ud654\ud559 B, 103, 37, 1999.9. \uc575\uac70 \ud654\ud559 Int. \uc5d0\ub4dc 2005, 44, 7053-7059. <\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"

UPAC separates pores into micropores (<2 nm), mesopores or mesopores (2 to 50 nm), macropores (> 50 nm) according to the pore size scale; according to the latest definition, the pores are subdivided into Micropores (<0.7 nm) and micropoles (0.7-2 nm), while wells below 100 nm are collectively referred to as nanopores. So how are…<\/p>","protected":false},"author":1,"featured_media":19668,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_jetpack_memberships_contains_paid_content":false,"footnotes":""},"categories":[79],"tags":[],"jetpack_featured_media_url":"https:\/\/www.meetyoucarbide.com\/wp-content\/uploads\/2019\/05\/141d2f_1ad683ac089a4a8dbd58302eb2e8e348-mv2.webp_-1.jpg","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/posts\/3756"}],"collection":[{"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/comments?post=3756"}],"version-history":[{"count":0,"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/posts\/3756\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/media\/19668"}],"wp:attachment":[{"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/media?parent=3756"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/categories?post=3756"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/ko\/wp-json\/wp\/v2\/tags?post=3756"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}