{"id":3756,"date":"2019-05-25T01:27:54","date_gmt":"2019-05-25T01:27:54","guid":{"rendered":"https:\/\/www.meetyoucarbide.com\/?p=3756"},"modified":"2020-05-07T07:46:20","modified_gmt":"2020-05-07T07:46:20","slug":"14-common-types-of-porous-materials","status":"publish","type":"post","link":"https:\/\/www.meetyoucarbide.com\/zh\/14%e7%a7%8d%e5%b8%b8%e8%a7%81%e7%9a%84%e5%a4%9a%e5%ad%94%e6%9d%90%e6%96%99\/","title":{"rendered":"14\u79cd\u5e38\u89c1\u7684\u591a\u5b54\u6750\u6599"},"content":{"rendered":"<div class=\"vgblk-rw-wrapper limit-wrapper\">\n<p> UPAC\u6839\u636e\u5b54\u5f84\u89c4\u6a21\u5c06\u5b54\u5212\u5206\u4e3a\u5fae\u5b54\uff08&lt;2 nm\uff09\uff0c\u4e2d\u5b54\u6216\u4e2d\u5b54\uff082\u81f350 nm\uff09\uff0c\u5927\u5b54\uff08&gt; 50 nm\uff09\uff1b\u6839\u636e\u6700\u65b0\u5b9a\u4e49\uff0c\u5c06\u5b54\u7ec6\u5206\u4e3a\u5fae\u5b54\uff08&lt;0.7 nm\uff09\u548c\u5fae\u6781\uff080.7-2 nm\uff09\uff0c\u800c\u4f4e\u4e8e100 nm\u7684\u5b54\u7edf\u79f0\u4e3a\u7eb3\u7c73\u5b54\u3002\u90a3\u4e48\u8fd9\u4e9b\u5b54\u6750\u6599\u7684\u540d\u79f0\u662f\u600e\u4e48\u6765\u7684\u5462\uff1f<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>MCM\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>MCM\u662fMobil Composition of Matter\u7684\u7b80\u79f0\u3002\u7531Mobil Oil\u7814\u7a76\u4eba\u5458\u4e3b\u8981\u4f7f\u7528\u7845\u9178\u4e59\u916f\u4f5c\u4e3a\u7845\u6e90\uff0c\u901a\u8fc7\u57fa\u4e8e\u80f6\u675f\u7684\u8f6f\u6a21\u677f\u65b9\u6cd5\u5408\u6210\u3002 MCM\u706b\u67aa\u624b\u662fMCM-41\uff0cMCM-48\u548cMCM-50\u3002 MCM-41\u662f\u516d\u89d2\u5f62\u7684\u4e2d\u5b54\u7ed3\u6784\uff0c\u7531\u4e00\u7ef4\u5b54\u7ed3\u6784\u5236\u6210\u7684\u89c4\u5219\u7684\u5706\u67f1\u5f62\u4e2d\u5b54\u6392\u5217\u3002\u4e2d\u5b54\u76f4\u5f84\u57282-6.5 nm\u4e4b\u95f4\u53ef\u8c03\uff0c\u6bd4\u8868\u9762\u79ef\u5927\u3002\u4e0e\u5206\u5b50\u7b5b\u76f8\u6bd4\uff0cMCM-41\u4e2d\u6ca1\u6709\u5e03\u6717\u65af\u53f0\u5fb7\u9178\u4f4d\u3002\u7531\u4e8e\u5176\u8584\u58c1\u548c\u7845\u5355\u5143\u7684\u4f4e\u4ea4\u6362\u7387\uff0cSi-O\u952e\u5728\u6cb8\u6c34\u4e2d\u6c34\u89e3\u5e76\u91cd\u65b0\u4ea4\u8054\uff0c\u4ece\u800c\u5bfc\u81f4\u7ed3\u6784\u7834\u574f\u3002\u56e0\u6b64\uff0c\u70ed\u7a33\u5b9a\u6027\u4e0d\u597d\u3002\u5173\u4e8eMCM-41\u5408\u6210\u7684\u6700\u65e9\u8bba\u6587\u53d1\u8868\u4e8e1992\u5e74\u7684JAC\u4e2d\uff0c\u88ab\u5f15\u7528\u7684\u6587\u732e\u73b0\u5df2\u63a5\u8fd112,000\u4e2a\u3002 \uff08J.Am.Chem.Soc\u3002\uff0c1992\uff0c114\uff0827\uff09\uff0cpp 10834-10843\u3002\uff09MCM-48\u5177\u6709\u4e09\u7ef4\u4e92\u8fde\u7684\u7ec6\u80de\u7ed3\u6784\u3002 MCM-50\u662f\u5c42\u72b6\u7ed3\u6784\uff0c\u53ea\u80fd\u88ab\u79f0\u4e3a\u201c\u4e2d\u5c42\u7ed3\u6784\u201d\uff0c\u800c\u4e0d\u662f\u201c\u4e2d\u5c42\u7684\u201d\uff0c\u56e0\u4e3a\u5c42\u72b6\u7ed3\u6784\u5728\u53bb\u9664\u8868\u9762\u6d3b\u6027\u5242\u5f62\u6210\u5c42\u65f6\u4f1a\u584c\u9677\uff0c\u5e76\u4e14\u7531\u4e8e\u6ca1\u6709\u5b54\uff0c\u56e0\u6b64\u6df1\u5ea6\u4e0d\u6df1\u3002<strong>&nbsp;<\/strong><\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_46ff3c3b900d4b97b7cf189378ba6327~mv2.jpg\/v1\/fill\/w_626,h_108\/141d2f_46ff3c3b900d4b97b7cf189378ba6327~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe1 MCM-41\u7684\u5408\u6210\u673a\u7406\u56fe\uff0c\u6240\u7528\u7684\u8868\u9762\u6d3b\u6027\u5242\u662f\u9634\u79bb\u5b50\u8868\u9762\u6d3b\u6027\u5242<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>SBA\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>SBA\u662fSanta Barbara Amorphous\u7684\u7f29\u5199\u3002\u5176\u4e2d\uff0c\u5927\u724c\u662fSBA-15\u3002 SBA-15\u6700\u521d\u662f\u7531\u590d\u65e6\u5927\u5b66\u7684\u8001\u5e08\u8d75\u4e1c\u5143\u5728\u7f8e\u56fd\u52a0\u5229\u798f\u5c3c\u4e9a\u5927\u5b66\u5723\u5854\u82ad\u82ad\u62c9\u5206\u6821\u8fdb\u884c\u4e86\u7814\u7a76\u751f\u5b66\u4e60\u540e\u4e8e1998\u5e74\u5408\u6210\u7684\u3002\u8be5\u5e74\u5728\u300a\u79d1\u5b66\u300b\u6742\u5fd7\u4e0a\u53d1\u8868\uff0c\u88ab\u5f15\u7528\u4e8610,000\u591a\u6b21\uff08 1998\u5e741\u670823\u65e5\uff0c\u79d1\u5b66\uff1a279\u30015350\u3001548-552\u3002 SBA\u7cfb\u5217\u4e2d\u5b54\u4e8c\u6c27\u5316\u7845\u6750\u6599\u662f\u4f7f\u7528\u5d4c\u6bb5\u578b\u8868\u9762\u6d3b\u6027\u5242\u901a\u8fc7\u8f6f\u6a21\u677f\u6cd5\u5408\u6210\u7684\u3002\u5176\u5b54\u5f84\u53ef\u57285-30 nm\u8303\u56f4\u5185\u8c03\u8282\u3002 SBA-15\u7531\u4e00\u7cfb\u5217\u516d\u8fb9\u5f62\u5e73\u884c\u5706\u67f1\u72b6\u901a\u9053\u7ec4\u6210\uff0c\u5e26\u6709\u4e00\u4e9b\u4e2d\u5b54\u6216\u5b54\uff0c\u5b83\u4eec\u968f\u673a\u6392\u5217\uff0c\u7ec6\u80de\u58c1\u539a\u5ea6\u4e3a3-6 nm\u3002\u7531\u4e8eSBA-15\u7684\u58c1\u539a\uff0c\u8be5\u6750\u6599\u7684\u6c34\u70ed\u7a33\u5b9a\u6027\u4f18\u4e8eMCM\u7cfb\u5217\u3002 SBA-15\u662f\u5305\u542b\u4e24\u79cd\u4e2d\u5b54\u6750\u6599\u7684\u591a\u7ef4\u591a\u5b54\u6750\u6599\u3002\u5b83\u53ef\u4ee5\u5728\u7145\u70e7\u8fc7\u7a0b\u4e2d\u53bb\u9664\u5d4c\u5165\u5728\u5b54\u58c1\u4e2d\u7684\u8868\u9762\u6d3b\u6027\u5242\uff0c\u4ece\u800c\u5f62\u6210\u5fae\u5b54\u7ed3\u6784\u3002<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_7f751cc065034eda91c0d26b85098751~mv2.jpg\/v1\/fill\/w_626,h_216\/141d2f_7f751cc065034eda91c0d26b85098751~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe2\uff08\u5de6\uff09\u5177\u6709\u4e0d\u540c\u5b54\u5f84\u7684SBA-15\u7684TEM\u56fe\u50cf\u3002 \uff08\u53f3\uff09\u4e09\u5d4c\u6bb5\u8868\u9762\u6d3b\u6027\u5242\u7684\u758f\u6c34\u7aef\u5c06\u8fdb\u5165\u5f62\u6210\u7684\u4e8c\u6c27\u5316\u7845\u7684\u5b54\u58c1\u3002\u7145\u70e7\u540e\uff0c\u5fae\u5b54<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>HMM\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>HMM\u662f\u5e7f\u5c9b\u4e2d\u5b54\u6750\u6599\u7684\u7f29\u5199\uff0c\u7531\u5e7f\u5c9b\u5927\u5b66\u7684\u7814\u7a76\u4eba\u5458\u4e8e2009\u5e74\u9996\u6b21\u5236\u5907\u3002HMM\u662f\u7403\u5f62\u4e2d\u5b54\u7845\u6750\u6599\uff0c\u5b54\u5f84\u4e3a4-15 nm\uff0c\u53ef\u8c03\u5916\u5f84\u4e3a20-80 nm\u3002\u5728\u5408\u6210\u6b65\u9aa4\u4e2d\uff0c\u4f5c\u8005\u9996\u5148\u901a\u8fc7\u6cb9\/\u6c34\/\u8868\u9762\u6d3b\u6027\u5242\u6df7\u5408\u6eb6\u6db2\u5f62\u6210\u4e73\u6db2\u6db2\u6ef4\uff0c\u7136\u540e\u4ee5\u539f\u4f4d\u751f\u6210\u7684\u805a\u82ef\u4e59\u70ef\u9897\u7c92\u4e3a\u6a21\u677f\u751f\u957f\u7845\uff0c\u5728\u53bb\u9664\u6a21\u677f\u540e\u751f\u6210\u7403\u5f62\u4e2d\u5b54\u4e8c\u6c27\u5316\u7845\u3002 \uff08\u5fae\u5b54\u548c\u4e2d\u5b54\u6750\u6599120\uff082009\uff09447-453\u3002\uff09<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_ec19c958087643228fba36b6f4b08fca~mv2.jpg\/v1\/fill\/w_626,h_286\/141d2f_ec19c958087643228fba36b6f4b08fca~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe3 HMM\u5408\u6210\u673a\u7406\u56fe\u4ee5\u53ca\u4ea7\u54c1SEM\u548cTEM\u56fe\u50cf<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>TUD\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>TUD\u4ee3\u8868\u4ee3\u5c14\u592b\u7279\u5de5\u4e1a\u5927\u5b66\uff0c\u53c8\u79f0\u4ee3\u5c14\u592b\u7279\u5de5\u4e1a\u5927\u5b66\u3002\u5728\u7535\u5b50\u663e\u5fae\u7167\u7247\u4e2d\uff0cTUD-1\u8868\u73b0\u4e3a\u6ce1\u6cab\uff0c\u8868\u9762\u79ef\u4e3a400-1000 m2 \/ g\uff0c\u53ef\u8c03\u4e2d\u5b54\u4ecb\u4e8e2.5\u81f325 nm\u4e4b\u95f4\u3002\u5728\u6750\u6599\u5408\u6210\u4e2d\uff0c\u6ca1\u6709\u8868\u9762\u6d3b\u6027\u5242\uff0c\u4e09\u4e59\u80fa\u7528\u4f5c\u6709\u673a\u6a21\u677f\u5242\u3002\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u6709\u673a\u6a21\u677f\u5242\u548c\u7845\u6e90\u7684\u6bd4\u4f8b\u6765\u63a7\u5236\u5b54\u7ed3\u6784\u3002 \uff08\u5316\u5b66\u516c\u62a5\uff0c2001\uff0c713-714\uff09<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_88526a701d9e4f9bb2df21af3e5bf2c0~mv2.jpg\/v1\/fill\/w_626,h_248\/141d2f_88526a701d9e4f9bb2df21af3e5bf2c0~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe4\uff08\u5de6\uff09TDU-1\u7684SEM\u56fe\u50cf\uff0c\uff08\u53f3\uff09\u4ee5TDU-1\u4e3a\u786c\u6a21\u677f\u5408\u6210\u7684\u4e2d\u5b54\u78b3\u6750\u6599<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>FSM\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>FSM\u662f\u6298\u53e0\u677f\u4ecb\u5b54\u6750\u6599\u7684\u7f29\u5199\u3002\u76f4\u8bd1\u7684\u540d\u79f0\u662f\uff0c\u6298\u53e0\u7684\u7247\u72b6\u4ecb\u5b54\u6750\u6599\u3002 FSM\u5408\u6210\u662f\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u5408\u6210\u5c42\u72b6\u7845\u9178\u76d0\u6750\u6599Kanemite\u548c\u957f\u94fe\u70f7\u57fa\u4e09\u7532\u80fa\uff08ATMA\uff09\u8fdb\u884c\u6df7\u5408\u5904\u7406\u540e\u53d1\u751f\u7684\u79bb\u5b50\u4ea4\u6362\uff0c\u4ece\u800c\u83b7\u5f97\u4e86\u7a84\u5b54\u5c3a\u5bf8\u5206\u5e03\u7684\u4e09\u7ef4\u516d\u89d2\u5f62\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u6750\u6599\u3002 FSC\u7684\u6bd4\u8868\u9762\u79ef\u4e3a650-1000 m2 \/ g\uff0c\u5b54\u5f84\u4e3a1.5-3 nm\u3002 \uff08Bull.Chem.Soc.Jpn\u3002\uff0c69\uff0cNo.5\uff081996\uff09\uff09<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_979e02d2480b448b9450ab4f132f5878~mv2.jpg\/v1\/fill\/w_626,h_225\/141d2f_979e02d2480b448b9450ab4f132f5878~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe5 FSM\u7684TEM\u56fe<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>\u5957\u4ef6\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>KIT\u627e\u4e0d\u5230\u975e\u5e38\u6b63\u5f0f\u7684\u58f0\u660e\uff0c\u5f88\u53ef\u80fd\u662fKorea Advanced Institute of Science and Technology\u7684\u7f29\u5199\u3002\u540c\u6837\u5c5e\u4e8e\u6709\u5e8f\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u6750\u6599\uff0c\u4e0d\u540c\u4e8eSBA-15\uff08\u7acb\u65b9p6mm\uff09\u5355\u5411\u5b54\u7ed3\u6784\uff0cKIT-6\uff08\u7acb\u65b9la3d\uff09\u5177\u6709\u76f8\u4e92\u8fde\u63a5\u7684\u7acb\u65b9\u4ecb\u5b54\u7ed3\u6784\u3002\u5728KIT-6\u7684\u5408\u6210\u4e2d\uff0c\u4f7f\u7528\u4e86\u4e09\u5d4c\u6bb5\u8868\u9762\u6d3b\u6027\u5242\uff08EO20PO70EO20\uff09\u548c\u4e01\u9187\u7684\u6df7\u5408\u7269\u4f5c\u4e3a\u7ed3\u6784\u5bfc\u5411\u5242\u3002 KIT-6\u5b54\u5f84\u53ef\u57284-12 nm\u8303\u56f4\u5185\u8c03\u8282\uff0c\u6bd4\u8868\u9762\u79ef\u4e3a960-2200 m2 g-1\u3002 \uff08\u5316\u5b66\u516c\u62a5\uff0c2003\uff0c2136-2137\uff09<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_43bb7a6b1ee34b1aab053da414da369c~mv2.jpg\/v1\/fill\/w_626,h_292\/141d2f_43bb7a6b1ee34b1aab053da414da369c~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe6\uff08\u5de6\uff09SBA-15 p6mm\u548cKIT-6 la3d\u7684\u7ed3\u6784\u56fe\uff0c\uff08\u53f3\uff09KIT-6\u7684TEM\u56fe\u50cf<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>CMK\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>\u5408\u6210\u4e2d\u5b54\u78b3\u7684\u5e38\u7528\u65b9\u6cd5\u662f\u786c\u6a21\u677f\u6cd5\u3002\u4ee5MCM-48\u548cSBA-15\u7b49\u4e2d\u5b54\u5206\u5b50\u7b5b\u4e3a\u6a21\u677f\u6765\u9009\u62e9\u5408\u9002\u7684\u524d\u4f53\uff0c\u5728\u9178\u7684\u50ac\u5316\u4e0b\u5c06\u524d\u4f53\u78b3\u5316\u5e76\u6c89\u79ef\u5728\u4e2d\u5b54\u9053\u7684\u5b54\u4e2d\uff0c\u7136\u540e\u7528NaOH\u6216HF\u4e2d\u5b54SiO2\u6eb6\u89e3\uff0c\u83b7\u5f97\u4e2d\u5b54\u78b3\u3002 1999\u5e74\uff0cRyoo\u4f7f\u7528\u4ecb\u5b54\u6750\u6599\u4f5c\u4e3a\u786c\u6a21\u677f\u6210\u529f\u590d\u5236\u4e86\u5176\u4ed6\u4ecb\u5b54\u6750\u6599\u3002\u8be5\u7cfb\u5217\u6750\u6599\u547d\u540d\u4e3aCMK\u3002\u4e5f\u6ca1\u6709\u627e\u5230\u6b63\u5f0f\u7684\u547d\u540d\uff0c\u4f46\u5f88\u53ef\u80fd\u662fCarbon Molecular Sieves\u548cKorea\u7684\u5408\u5e76\u547d\u540d\u3002\u4ed6\u5148\u540e\u4ee5MCM-48\uff0cSBA-1\uff0cSBA-15\u548cKIT-6\u4e3a\u6a21\u677f\uff0c\u751f\u4ea7\u4e86CMK-1\uff0cCMK-2\uff0cCMK-3\uff0cCMK-8\u548cCMK-9\u4ecb\u5b54\u78b3\u5206\u5b50\u7b5b\u6750\u6599\u3002 \uff08J. Phys\u3002Chem\u3002B\uff0c103\uff0c37\uff0c1999.\uff09CMK-3\u662f\u4e8c\u7ef4\u516d\u8fb9\u5f62\u7ed3\u6784\uff0c\u5177\u6709\u72ed\u7a84\u7684\u5b54\u5f84\u5206\u5e03\uff0c\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff081000-2000 m2 \/ g\uff09\uff0c\u5927\u7684\u5b54\u4f53\u79ef1.35 cm3 \/ g\uff09\u548c\u5f3a\u7684\u8010\u9178\u78b1\u6027\uff0c\u662f\u826f\u597d\u7684\u50ac\u5316\u5242\u8f7d\u4f53\u3002<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_f337e0b0b1254511b7250a75e1f82c43~mv2.jpg\/v1\/fill\/w_626,h_368\/141d2f_f337e0b0b1254511b7250a75e1f82c43~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe7 CMK-1\u548cCMK-3\u7684TEM\u56fe\u50cf<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>FDU\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>FDU\u7cfb\u5217\u662f\u590d\u65e6\u5927\u5b66\u7684\u7f29\u5199\uff0c\u662f\u8d75\u4e1c\u5143\u8001\u5e08\u56de\u5230\u590d\u65e6\u5927\u5b66\u540e\u6240\u505a\u7684\u5de5\u4f5c\u3002 FDU\u662f\u901a\u8fc7\u8f6f\u6a21\u677f\u6cd5\u5408\u6210\u7684\u4e00\u7cfb\u5217\u915a\u919b\u6811\u8102\u3002\u6709\u5e8f\u7684\u4ecb\u5b54\u78b3\u6750\u6599\u53ef\u4ee5\u901a\u8fc7\u9ad8\u6e29\u78b3\u5316\u6765\u5408\u6210\uff0c\u5e76\u4e14\u7531\u7403\u5f62\u5b54\u7ec4\u6210\u3002\u540c\u6837\u662f\u4f7f\u7528\u8868\u9762\u6d3b\u6027\u5242\u4f5c\u4e3a\u7ed3\u6784\u5bfc\u5411\u5242\uff0c\u4f7f\u7528\u915a\u919b\u6811\u8102\u524d\u4f53\u4e3a\u539f\u6599\uff0c\u901a\u8fc7\u6eb6\u5242\u84b8\u53d1\u81ea\u7ec4\u88c5\u6cd5\u5f97\u5230\u6709\u5e8f\u7684\u7ed3\u6784\u3002 \uff08Angew.Chem.Int.Ed.2005\uff0c44\uff0c7053-7045\uff09<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_957b09d255d8487fb64fa290cbc36ba9~mv2.jpg\/v1\/fill\/w_626,h_314\/141d2f_957b09d255d8487fb64fa290cbc36ba9~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe8\u9ad8\u6e29\u78b3\u5316\u540e\u7684FDU-15\u548cFDU-16<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>STARBON\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>Starbon\u662f\u4ecb\u5b54\u78b3\u6750\u6599\u7684\u540d\u79f0\u3002\u56e0\u4e3a\u6700\u521d\u7684Starbon\u662f\u7531\u7ea6\u514b\u5927\u5b66\u7684\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u6dc0\u7c89\u7684\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u5408\u6210\u7684\uff0c\u7136\u540e\u78b3\u5316\u4e86\u3002\u56e0\u6b64\uff0c\u5176\u540d\u79f0\u4e3aStarbon\uff0c\u5e76\u6ce8\u518c\u4e86\u5546\u6807\u540d\u79f0\u201c Starbon\u201d\u3002 Starbon\u4e2d\u5b54\u4f53\u79ef\u4e3a2.0 cm3 \/ g\uff0c\u6bd4\u8868\u9762\u79ef\u4e3a500 m2 \/ g\uff0c\u53ef\u7528\u4f5c\u50ac\u5316\u5242\u8f7d\u4f53\uff0c\u6c14\u4f53\u5438\u9644\u5242\u6216\u51c0\u6c34\u5242\u3002\u73b0\u5728\uff0cStarbon\u539f\u6599\u53ef\u4ee5\u6269\u5c55\u5230\u679c\u80f6\u548c\u85fb\u9178\u3002<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_50308e7656d140a1956aa9c05a86f737~mv2.jpg\/v1\/fill\/w_626,h_160\/141d2f_50308e7656d140a1956aa9c05a86f737~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe9\uff08\u5de6\uff09Starbon\u5408\u6210\u6b65\u9aa4\uff0c\uff08\u53f3\uff09Starbon\u7684SEM\u56fe\u50cf<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>ZSM\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>ZSM\u662fSocony Mobil\u6cb8\u77f3\u7684\u7f29\u5199\uff0cZSM-5\u662f\u5546\u54c1\u540d\uff0c\u662fSocony Mobil Corporation\u53d1\u73b0\u7684\u7b2c\u4e94\u79cd\u6cb8\u77f3\u3002 Nature\u4e8e1975\u5e74\u8fdb\u884c\u4e86\u5408\u6210\uff0c\u5e76\u4e8e1978\u5e74\u62a5\u544a\u4e86\u5176\u7ed3\u6784\u3002ZSM-5\u662f\u6b63\u4ea4\u6676\u7cfb\u3002\u5b83\u662f\u4e00\u79cd\u5177\u6709\u9ad8\u7845\u548c\u4e94\u5143\u73af\u7684\u4e09\u7ef4\u4ea4\u53c9\u901a\u9053\u7684\u6cb8\u77f3\u5206\u5b50\u7b5b\u3002\u5b83\u5177\u6709\u4eb2\u6cb9\u6027\u548c\u758f\u6c34\u6027\uff0c\u5177\u6709\u5f88\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u6c34\u70ed\u7a33\u5b9a\u6027\uff0c\u5e76\u4e14\u5927\u591a\u6570\u5b54\u7684\u76f4\u5f84\u7ea6\u4e3a0.55 nm\u3002<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_515e439f4f714ac581c3dba0eb10963d~mv2.jpg\/v1\/fill\/w_322,h_245\/141d2f_515e439f4f714ac581c3dba0eb10963d~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe10 TPABr\u5408\u6210\u7684ZSM-5<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>AlPO\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>AlPO\u662f\u65e0\u9178\u7684\u5fae\u5b54\u94dd\u78f7\u9178\u76d0\u5206\u5b50\u7b5b\u7684\u7f29\u5199\uff0c\u5b83\u662f\u7f8e\u56fdUOP\u516c\u53f8\u81ea1980\u5e74\u4ee3\u4ee5\u6765\u5f00\u53d1\u7684\u201c\u7b2c\u4e8c\u4ee3\u5206\u5b50\u7b5b\u201d\u3002\u8fd9\u4e9b\u5206\u5b50\u7b5b\u9aa8\u67b6\u7531\u7b49\u91cf\u7684AlO4-\u548cPO4-\u56db\u9762\u4f53\u7ec4\u6210\uff0c\u5e76\u4e14\u662f\u7535\u4e2d\u6027\u7684\uff0c\u5e76\u4e14\u663e\u793a\u51fa\u8f83\u5f31\u7684\u9178\u50ac\u5316\u6027\u80fd\u3002\u968f\u7740\u6742\u539f\u5b50\u7684\u5f15\u5165\uff0c\u53ef\u4ee5\u7834\u574fAlPO\u6cb8\u77f3\u9aa8\u67b6\u7684\u539f\u59cb\u7535\u8377\u5e73\u8861\uff0c\u4ece\u800c\u663e\u7740\u63d0\u9ad8\u5176\u9178\u5ea6\uff0c\u5438\u9644\u6027\u80fd\u548c\u50ac\u5316\u6d3b\u6027\u3002 AlPO4-5\u7684\u9aa8\u67b6\u7ed3\u6784\u5c5e\u4e8e\u516d\u89d2\u5f62\u4f53\u7cfb\uff0c\u5177\u6709\u5178\u578b\u768412\u5143\u73af\u4e3b\u901a\u9053\uff0c\u5176\u5b54\u5f84\u4e3a0.76 nm\uff0c\u4e0e\u82b3\u65cf\u5316\u5408\u7269\u7684\u5b54\u5f84\u76f8\u5f53\u3002<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>SAPO\u7cfb\u5217<\/strong><\/h2>\n\n\n\n<p>SAPO\u662f\u7845\u94dd\u78f7\u9178\u76d0\u7684\u7f29\u5199\uff0cSAPO-34\u662fUCC\u4e8e1982\u5e74\u9996\u6b21\u62a5\u9053\u7684\u5206\u5b50\u7b5b\uff0c\u800c\u4ee3\u53f7\u4e3a34\u3002 SAPO-34\u7684\u9aa8\u67b6\u7531PO2 +\uff0cSiO2\uff0cAlO2-\u7ec4\u6210\uff0c\u5e76\u5177\u6709\u4e09\u7ef4\u4ea4\u53c9\u901a\u9053\uff0c\u516b\u73af\u5b54\u5f84\u548c\u4e2d\u7b49\u9178\u4f4d\u3002\u4ee5\u53ca\u5438\u9644\u5206\u79bb\u548c\u819c\u5206\u79bb\u5747\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002 SAPO-11\u7684\u6210\u5206\u4e3aSi\uff0cP\uff0cAl\u548cO\u56db\u79cd\uff0c\u5176\u6210\u5206\u53ef\u5728\u8f83\u5927\u8303\u56f4\u5185\u53d8\u5316\uff0c\u4ea7\u7269\u4e2d\u7684\u7845\u542b\u91cf\u968f\u5408\u6210\u6761\u4ef6\u800c\u53d8\u5316\u3002\u5177\u6709\u4e00\u7ef4\u5341\u73af\u7ed3\u6784\u7684SAPO-11\u4ecb\u5b54\u6cb8\u77f3\u6210\u5375\u5f62\u5b54\u3002 SAPO\u5206\u5b50\u7b5b\u9aa8\u67b6\u5e26\u8d1f\u7535\uff0c\u56e0\u6b64\u5177\u6709\u53ef\u4ea4\u6362\u7684\u9633\u79bb\u5b50\u5e76\u5177\u6709\u8d28\u5b50\u9178\u5ea6\u3002 SAPO\u5206\u5b50\u7b5b\u53ef\u7528\u4f5c\u5438\u9644\u5242\uff0c\u50ac\u5316\u5242\u548c\u50ac\u5316\u5242\u8f7d\u4f53\u3002<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img decoding=\"async\" src=\"\/\/static.wixstatic.com\/media\/141d2f_f90ee7a461614ed69aaba2d46680f1ae~mv2.jpg\/v1\/fill\/w_612,h_478\/141d2f_f90ee7a461614ed69aaba2d46680f1ae~mv2.jpg\" alt=\"\" title=\"\"><figcaption> <strong>\u56fe11\u7ed3\u6676\u65f6\u95f4\u4e3a48h\u7684SAPO-11\u7684SEM\u56fe\u50cf<\/strong> <\/figcaption><\/figure><\/div>\n\n\n\n<p><br>\u8fd8\u6709\u5176\u4ed6\u51e0\u79cd\u4e0d\u5e38\u7528\u7684\u591a\u5b54\u6750\u6599\uff1a<br><strong>\u5bc6\u897f\u6839\u5dde\u7acb\u5927\u5b66 <\/strong>&nbsp;\uff08\u5bc6\u6b47\u6839\u5dde\u7acb\u5927\u5b66\uff09\u662fPinnavaia\u7b49\u4eba\u5f00\u53d1\u7684\u4e00\u7cfb\u5217\u4ecb\u5b54\u5206\u5b50\u7b5b\u3002\u5bc6\u897f\u6839\u5927\u5b66\u3002 MSU-X\uff08MSU-1\uff0cMSU-2\u548cMSU-3\uff09\u3002 MSU-V\uff0cMSU-G\u5177\u6709\u591a\u5c42\u56ca\u6ce1\u7684\u5206\u5c42\u7ed3\u6784\u3002<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>HMS <\/strong><\/h2>\n\n\n\n<p>\uff08\u516d\u89d2\u4e2d\u5b54\u4e8c\u6c27\u5316\u7845\uff09\u662f\u7531Pinnavaia\u7b49\u4eba\u5f00\u53d1\u7684\u4e2d\u5b54\u5206\u5b50\u7b5b\uff0c\u4e5f\u662f\u5177\u6709\u4f4e\u5e8f\u5ea6\u7684\u516d\u8fb9\u5f62\u7ed3\u6784\u3002<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>APM<\/strong> <\/h2>\n\n\n\n<p>\uff08\u9178\u5236\u5907\u7684\u4ecb\u5b54\u7ed3\u6784\uff09\u662fStucky\u7b49\u4eba\u7684\u65e9\u671f\u7814\u7a76\uff0c\u662f\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u5236\u5907\u7684\uff0c\u662fMCM\u7cfb\u5217\u5408\u6210\u65b9\u6cd5\uff08\u78b1\u6027\u4ecb\u8d28\uff09\u7684\u5ef6\u4f38\u3002<br>\u4e0d\u4ec5\u540d\u79f0\u975e\u5e38\u72ec\u7279\uff0c\u800c\u4e14\u591a\u5b54\u6750\u6599\u7684\u5e94\u7528\u4e5f\u975e\u5e38\u5e7f\u6cdb\uff0c\u4e3b\u8981\u6709\uff1a<\/p>\n\n\n\n<p>1.\u9ad8\u6548\u7684\u6c14\u4f53\u5206\u79bb\u819c\uff1b<\/p>\n\n\n\n<p>2.\u5316\u5b66\u8fc7\u7a0b\u50ac\u5316\u819c\uff1b<\/p>\n\n\n\n<p>3.\u7528\u4e8e\u9ad8\u901f\u7535\u5b50\u7cfb\u7edf\u7684\u57fa\u677f\u6750\u6599\uff1b<\/p>\n\n\n\n<p>4.\u5149\u901a\u4fe1\u6750\u6599\u7684\u524d\u4f53\uff1b<\/p>\n\n\n\n<p>5.\u9ad8\u6548\u4fdd\u6e29\u6750\u6599\uff1b<\/p>\n\n\n\n<p>6.\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u7684\u591a\u5b54\u7535\u6781\uff1b<\/p>\n\n\n\n<p>7.\u7535\u6c60\u7684\u5206\u79bb\u4ecb\u8d28\u548c\u7535\u6781\uff1b<\/p>\n\n\n\n<p>8.\u71c3\u6599\uff08\u5305\u62ec\u5929\u7136\u6c14\u548c\u6c22\u6c14\uff09\u7684\u5b58\u50a8\u4ecb\u8d28\uff1b <\/p>\n\n\n\n<p>9.\u9009\u62e9\u73af\u4fdd\u6e05\u6d01\u7684\u5438\u6536\u5242\uff1b<\/p>\n\n\n\n<p>10.\u7279\u6b8a\u7684\u53ef\u91cd\u590d\u4f7f\u7528\u7684\u8fc7\u6ee4\u5668\u3002\u8fd9\u4e9b\u5e94\u7528\u5c06\u5bf9\u5de5\u4e1a\u5e94\u7528\u548c\u4eba\u4eec\u7684\u65e5\u5e38\u751f\u6d3b\u4ea7\u751f\u6df1\u8fdc\u7684\u5f71\u54cd\u3002<\/p>\n\n\n\n<p><br><strong>\u53c2\u8003\u6587\u732e\uff1a<\/strong>1. J. Am\u3002\u5316\u5b66Soc\u3002\uff0c1992\uff0c114\uff0827\uff09\uff0c\u7b2c10834-10843.2\u3002 1998\u5e741\u670823\u65e5\uff0c\u79d1\u5b66\uff1a279\u30015350\u3001548-552.3\u3002\u5fae\u5b54\u548c\u4e2d\u5b54\u6750\u6599120\uff082009\uff09447-453.4\u3002\u5316\u5b66Commun\u3002\uff0c2001\uff0c713-714.5\u3002\u516c\u725b\u3002\u5316\u5b66Soc\u3002 Jpn.69\uff0cNo.5\uff081996\uff096\u3002 J.\u5316\u5b66\u5316\u5b66\uff0c\u5316\u5b66\u3002\u516c\u793e1993\uff0c8\uff0c680.7\u3002\u5316\u5b66Commun\u3002\uff0c2003\uff0c2136-2137.8\u3002 J.\u7269\u7406\u5316\u5b66B\uff0c103\uff0c37\uff0c1999.9\u3002 Angew\u3002\u5316\u5b66\u8be0\u91ca\u57c3\u5fb72005\uff0c44\uff0c7053-7059\u3002 <\/p>\n<\/div><!-- .vgblk-rw-wrapper -->","protected":false},"excerpt":{"rendered":"<p>UPAC separates pores into micropores (&lt;2 nm), mesopores or mesopores (2 to 50 nm), macropores (&gt; 50 nm) according to the pore size scale; according to the latest definition, the pores are subdivided into Micropores (&lt;0.7 nm) and micropoles (0.7-2 nm), while wells below 100 nm are collectively referred to as nanopores. So how are&#8230;<\/p>","protected":false},"author":1,"featured_media":19668,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_jetpack_memberships_contains_paid_content":false,"footnotes":""},"categories":[79],"tags":[],"jetpack_featured_media_url":"https:\/\/www.meetyoucarbide.com\/wp-content\/uploads\/2019\/05\/141d2f_1ad683ac089a4a8dbd58302eb2e8e348-mv2.webp_-1.jpg","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/posts\/3756"}],"collection":[{"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/comments?post=3756"}],"version-history":[{"count":0,"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/posts\/3756\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/media\/19668"}],"wp:attachment":[{"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/media?parent=3756"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/categories?post=3756"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.meetyoucarbide.com\/zh\/wp-json\/wp\/v2\/tags?post=3756"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}